Water and Its Properties

The unique properties of water and their importance to life

💧 Water and Its Properties

Why Water is Essential for Life

Water (H₂O) is the most abundant molecule in living organisms and possesses unique properties critical for life.

Molecular Structure

Polarity:

  • Oxygen is more electronegative than hydrogen
  • Creates partial negative charge (δ-) on oxygen
  • Creates partial positive charge (δ+) on hydrogens
  • Bent molecular geometry (104.5° bond angle)

Hydrogen Bonding:

  • Weak attractions between water molecules
  • δ+ hydrogen attracted to δ- oxygen of another molecule
  • Each water molecule can form up to 4 hydrogen bonds

Key Properties of Water

1. Cohesion and Adhesion

Cohesion: Water molecules stick to each other (enables surface tension, water transport) Adhesion: Water molecules stick to other polar surfaces (capillary action)

2. High Specific Heat Capacity

  • Requires significant energy to change temperature
  • Stabilizes body temperature and moderates climate

3. High Heat of Vaporization

  • Evaporative cooling (sweating, transpiration)

4. Ice Floats

  • Lower density as solid due to crystalline structure
  • Insulates aquatic life in winter

5. Excellent Solvent

  • Dissolves polar and ionic substances
  • Forms hydration shells around ions

Hydrophobic vs. Hydrophilic

Hydrophilic: Polar molecules that dissolve in water Hydrophobic: Nonpolar molecules that don't dissolve in water Amphipathic: Molecules with both regions (e.g., phospholipids)

pH and Buffers

Water ionization: H₂O ⇌ H⁺ + OH⁻

  • pH = -log[H⁺]
  • pH 7 = neutral; <7 = acidic; >7 = basic
  • Buffers resist pH changes

📚 Practice Problems

1Problem 1easy

Question:

Explain why ice floats on water and describe the biological significance of this property for aquatic ecosystems during winter.

💡 Show Solution

Why Ice Floats:

Water has maximum density at 4°C. When water freezes at 0°C, it forms a crystalline structure with hydrogen bonds holding molecules in fixed positions, creating more space between molecules.

Key Points:

  • Ice has lower density (0.92 g/cm³) than liquid water (1.0 g/cm³)
  • Hydrogen bonds in ice create hexagonal lattice structure
  • This structure is less dense than liquid water's arrangement

Biological Significance:

  1. Insulation: Ice layer on top insulates water below, keeping it liquid
  2. Habitat preservation: Aquatic organisms can survive in liquid water under ice
  3. Temperature moderation: Water below ice stays near 4°C (maximum density)
  4. Prevents complete freezing: Lakes freeze from top down, not bottom up

Ecological Impact:

Without this property, lakes and ponds would freeze solid from the bottom up, killing most aquatic life. The ice layer acts as an insulating blanket, allowing fish, plants, and other organisms to survive winter in the liquid water below.

Ice floats because hydrogen bonding creates a less dense crystalline structure\boxed{\text{Ice floats because hydrogen bonding creates a less dense crystalline structure}}

2Problem 2easy

Question:

Explain why ice floats on water and describe the biological significance of this property for aquatic ecosystems during winter.

💡 Show Solution

Why Ice Floats:

Water has maximum density at 4°C. When water freezes at 0°C, it forms a crystalline structure with hydrogen bonds holding molecules in fixed positions, creating more space between molecules.

Key Points:

  • Ice has lower density (0.92 g/cm³) than liquid water (1.0 g/cm³)
  • Hydrogen bonds in ice create hexagonal lattice structure
  • This structure is less dense than liquid water's arrangement

Biological Significance:

  1. Insulation: Ice layer on top insulates water below, keeping it liquid
  2. Habitat preservation: Aquatic organisms can survive in liquid water under ice
  3. Temperature moderation: Water below ice stays near 4°C (maximum density)
  4. Prevents complete freezing: Lakes freeze from top down, not bottom up

Ecological Impact:

Without this property, lakes and ponds would freeze solid from the bottom up, killing most aquatic life. The ice layer acts as an insulating blanket, allowing fish, plants, and other organisms to survive winter in the liquid water below.

Ice floats because hydrogen bonding creates a less dense crystalline structure\boxed{\text{Ice floats because hydrogen bonding creates a less dense crystalline structure}}

3Problem 3easy

Question:

Explain why ice floats on water and describe the biological significance of this property for aquatic ecosystems during winter.

💡 Show Solution

Why Ice Floats:

Water has maximum density at 4°C. When water freezes at 0°C, it forms a crystalline structure with hydrogen bonds holding molecules in fixed positions, creating more space between molecules.

Key Points:

  • Ice has lower density (0.92 g/cm³) than liquid water (1.0 g/cm³)
  • Hydrogen bonds in ice create hexagonal lattice structure
  • This structure is less dense than liquid water's arrangement

Biological Significance:

  1. Insulation: Ice layer on top insulates water below, keeping it liquid
  2. Habitat preservation: Aquatic organisms can survive in liquid water under ice
  3. Temperature moderation: Water below ice stays near 4°C (maximum density)
  4. Prevents complete freezing: Lakes freeze from top down, not bottom up

Ecological Impact:

Without this property, lakes and ponds would freeze solid from the bottom up, killing most aquatic life. The ice layer acts as an insulating blanket, allowing fish, plants, and other organisms to survive winter in the liquid water below.

Ice floats because hydrogen bonding creates a less dense crystalline structure\boxed{\text{Ice floats because hydrogen bonding creates a less dense crystalline structure}}

4Problem 4easy

Question:

Explain why ice floats on water and describe the biological significance of this property for aquatic ecosystems during winter.

💡 Show Solution

Why Ice Floats:

Water has maximum density at 4°C. When water freezes at 0°C, it forms a crystalline structure with hydrogen bonds holding molecules in fixed positions, creating more space between molecules.

Key Points:

  • Ice has lower density (0.92 g/cm³) than liquid water (1.0 g/cm³)
  • Hydrogen bonds in ice create hexagonal lattice structure
  • This structure is less dense than liquid water's arrangement

Biological Significance:

  1. Insulation: Ice layer on top insulates water below, keeping it liquid
  2. Habitat preservation: Aquatic organisms can survive in liquid water under ice
  3. Temperature moderation: Water below ice stays near 4°C (maximum density)
  4. Prevents complete freezing: Lakes freeze from top down, not bottom up

Ecological Impact:

Without this property, lakes and ponds would freeze solid from the bottom up, killing most aquatic life. The ice layer acts as an insulating blanket, allowing fish, plants, and other organisms to survive winter in the liquid water below.

Ice floats because hydrogen bonding creates a less dense crystalline structure\boxed{\text{Ice floats because hydrogen bonding creates a less dense crystalline structure}}

5Problem 5medium

Question:

A plant cell is placed in a hypotonic solution. Using your knowledge of water's properties, explain: (a) what happens to the cell, (b) why water moves into the cell, and (c) what prevents the cell from bursting.

💡 Show Solution

Given: Plant cell in hypotonic solution (lower solute concentration outside)

(a) What happens to the cell:

Water moves into the cell by osmosis. The cell swells and becomes turgid (firm).

(b) Why water moves into the cell:

Osmosis: Water moves from high water concentration (low solute) to low water concentration (high solute) across a selectively permeable membrane.

  • Outside: hypotonic (more water molecules, fewer solutes)
  • Inside: hypertonic relative to outside (less water, more solutes)
  • Water potential: Ψoutside>Ψinside\Psi_{outside} > \Psi_{inside}

Water moves down its concentration gradient into the cell.

Mechanism:

  • Water is polar (partial charges due to bent shape and O-H bonds)
  • Moves through aquaporins (water channel proteins)
  • Follows concentration gradient until equilibrium

(c) What prevents bursting:

Cell wall provides structural support!

  • Made of cellulose (rigid polysaccharide)
  • Prevents excessive expansion
  • Creates turgor pressure (pressure of cell contents against wall)
  • Turgor pressure eventually equals osmotic pressure → equilibrium

Comparison to animal cells:

  • Animal cells lack cell walls
  • Would lyse (burst) in hypotonic solution
  • Plant cells become turgid but don't burst

Cell wall prevents bursting; turgor pressure maintains plant rigidity\boxed{\text{Cell wall prevents bursting; turgor pressure maintains plant rigidity}}

6Problem 6medium

Question:

A plant cell is placed in a hypotonic solution. Using your knowledge of water's properties, explain: (a) what happens to the cell, (b) why water moves into the cell, and (c) what prevents the cell from bursting.

💡 Show Solution

Given: Plant cell in hypotonic solution (lower solute concentration outside)

(a) What happens to the cell:

Water moves into the cell by osmosis. The cell swells and becomes turgid (firm).

(b) Why water moves into the cell:

Osmosis: Water moves from high water concentration (low solute) to low water concentration (high solute) across a selectively permeable membrane.

  • Outside: hypotonic (more water molecules, fewer solutes)
  • Inside: hypertonic relative to outside (less water, more solutes)
  • Water potential: Ψoutside>Ψinside\Psi_{outside} > \Psi_{inside}

Water moves down its concentration gradient into the cell.

Mechanism:

  • Water is polar (partial charges due to bent shape and O-H bonds)
  • Moves through aquaporins (water channel proteins)
  • Follows concentration gradient until equilibrium

(c) What prevents bursting:

Cell wall provides structural support!

  • Made of cellulose (rigid polysaccharide)
  • Prevents excessive expansion
  • Creates turgor pressure (pressure of cell contents against wall)
  • Turgor pressure eventually equals osmotic pressure → equilibrium

Comparison to animal cells:

  • Animal cells lack cell walls
  • Would lyse (burst) in hypotonic solution
  • Plant cells become turgid but don't burst

Cell wall prevents bursting; turgor pressure maintains plant rigidity\boxed{\text{Cell wall prevents bursting; turgor pressure maintains plant rigidity}}

7Problem 7medium

Question:

A plant cell is placed in a hypotonic solution. Using your knowledge of water's properties, explain: (a) what happens to the cell, (b) why water moves into the cell, and (c) what prevents the cell from bursting.

💡 Show Solution

Given: Plant cell in hypotonic solution (lower solute concentration outside)

(a) What happens to the cell:

Water moves into the cell by osmosis. The cell swells and becomes turgid (firm).

(b) Why water moves into the cell:

Osmosis: Water moves from high water concentration (low solute) to low water concentration (high solute) across a selectively permeable membrane.

  • Outside: hypotonic (more water molecules, fewer solutes)
  • Inside: hypertonic relative to outside (less water, more solutes)
  • Water potential: Ψoutside>Ψinside\Psi_{outside} > \Psi_{inside}

Water moves down its concentration gradient into the cell.

Mechanism:

  • Water is polar (partial charges due to bent shape and O-H bonds)
  • Moves through aquaporins (water channel proteins)
  • Follows concentration gradient until equilibrium

(c) What prevents bursting:

Cell wall provides structural support!

  • Made of cellulose (rigid polysaccharide)
  • Prevents excessive expansion
  • Creates turgor pressure (pressure of cell contents against wall)
  • Turgor pressure eventually equals osmotic pressure → equilibrium

Comparison to animal cells:

  • Animal cells lack cell walls
  • Would lyse (burst) in hypotonic solution
  • Plant cells become turgid but don't burst

Cell wall prevents bursting; turgor pressure maintains plant rigidity\boxed{\text{Cell wall prevents bursting; turgor pressure maintains plant rigidity}}

8Problem 8medium

Question:

A plant cell is placed in a hypotonic solution. Using your knowledge of water's properties, explain: (a) what happens to the cell, (b) why water moves into the cell, and (c) what prevents the cell from bursting.

💡 Show Solution

Given: Plant cell in hypotonic solution (lower solute concentration outside)

(a) What happens to the cell:

Water moves into the cell by osmosis. The cell swells and becomes turgid (firm).

(b) Why water moves into the cell:

Osmosis: Water moves from high water concentration (low solute) to low water concentration (high solute) across a selectively permeable membrane.

  • Outside: hypotonic (more water molecules, fewer solutes)
  • Inside: hypertonic relative to outside (less water, more solutes)
  • Water potential: Ψoutside>Ψinside\Psi_{outside} > \Psi_{inside}

Water moves down its concentration gradient into the cell.

Mechanism:

  • Water is polar (partial charges due to bent shape and O-H bonds)
  • Moves through aquaporins (water channel proteins)
  • Follows concentration gradient until equilibrium

(c) What prevents bursting:

Cell wall provides structural support!

  • Made of cellulose (rigid polysaccharide)
  • Prevents excessive expansion
  • Creates turgor pressure (pressure of cell contents against wall)
  • Turgor pressure eventually equals osmotic pressure → equilibrium

Comparison to animal cells:

  • Animal cells lack cell walls
  • Would lyse (burst) in hypotonic solution
  • Plant cells become turgid but don't burst

Cell wall prevents bursting; turgor pressure maintains plant rigidity\boxed{\text{Cell wall prevents bursting; turgor pressure maintains plant rigidity}}

9Problem 9hard

Question:

Calculate the water potential (Ψ) of a plant cell with a solute potential (Ψ_s) of -0.5 MPa and a pressure potential (Ψ_p) of 0.3 MPa. If this cell is placed in a solution with Ψ = -0.3 MPa, will water move into or out of the cell? Show your work.

💡 Show Solution

Given:

  • Cell solute potential: Ψ_s = -0.5 MPa
  • Cell pressure potential: Ψ_p = 0.3 MPa
  • Solution water potential: Ψ_solution = -0.3 MPa

Step 1: Calculate cell water potential

Ψcell=Ψs+Ψp\Psi_{cell} = \Psi_s + \Psi_p

Ψcell=(0.5)+(0.3)\Psi_{cell} = (-0.5) + (0.3)

Ψcell=0.2 MPa\boxed{\Psi_{cell} = -0.2 \text{ MPa}}

Step 2: Determine direction of water movement

Water moves from higher (less negative) to lower (more negative) water potential.

Compare:

  • Ψcell=0.2\Psi_{cell} = -0.2 MPa
  • Ψsolution=0.3\Psi_{solution} = -0.3 MPa

Since 0.2>0.3-0.2 > -0.3:

Water moves OUT of the cell into the solution\boxed{\text{Water moves OUT of the cell into the solution}}

Step 3: Explanation

The cell has a higher (less negative) water potential than the surrounding solution, so water flows out by osmosis.

What happens to the cell:

  • Water exits the cell
  • Cell becomes flaccid (loses turgor)
  • May undergo plasmolysis (membrane pulls away from cell wall)
  • Ψ_p decreases as cell loses water
  • Eventually reaches equilibrium when Ψcell=Ψsolution\Psi_{cell} = \Psi_{solution}

Key Concept: Water always flows from high Ψ to low Ψ. More negative = lower water potential = less "free" water available.

Direction: CellwaterSolution\text{Direction: Cell} \xrightarrow{\text{water}} \text{Solution}

10Problem 10hard

Question:

Calculate the water potential (Ψ) of a plant cell with a solute potential (Ψ_s) of -0.5 MPa and a pressure potential (Ψ_p) of 0.3 MPa. If this cell is placed in a solution with Ψ = -0.3 MPa, will water move into or out of the cell? Show your work.

💡 Show Solution

Given:

  • Cell solute potential: Ψ_s = -0.5 MPa
  • Cell pressure potential: Ψ_p = 0.3 MPa
  • Solution water potential: Ψ_solution = -0.3 MPa

Step 1: Calculate cell water potential

Ψcell=Ψs+Ψp\Psi_{cell} = \Psi_s + \Psi_p

Ψcell=(0.5)+(0.3)\Psi_{cell} = (-0.5) + (0.3)

Ψcell=0.2 MPa\boxed{\Psi_{cell} = -0.2 \text{ MPa}}

Step 2: Determine direction of water movement

Water moves from higher (less negative) to lower (more negative) water potential.

Compare:

  • Ψcell=0.2\Psi_{cell} = -0.2 MPa
  • Ψsolution=0.3\Psi_{solution} = -0.3 MPa

Since 0.2>0.3-0.2 > -0.3:

Water moves OUT of the cell into the solution\boxed{\text{Water moves OUT of the cell into the solution}}

Step 3: Explanation

The cell has a higher (less negative) water potential than the surrounding solution, so water flows out by osmosis.

What happens to the cell:

  • Water exits the cell
  • Cell becomes flaccid (loses turgor)
  • May undergo plasmolysis (membrane pulls away from cell wall)
  • Ψ_p decreases as cell loses water
  • Eventually reaches equilibrium when Ψcell=Ψsolution\Psi_{cell} = \Psi_{solution}

Key Concept: Water always flows from high Ψ to low Ψ. More negative = lower water potential = less "free" water available.

Direction: CellwaterSolution\text{Direction: Cell} \xrightarrow{\text{water}} \text{Solution}

11Problem 11hard

Question:

Calculate the water potential (Ψ) of a plant cell with a solute potential (Ψ_s) of -0.5 MPa and a pressure potential (Ψ_p) of 0.3 MPa. If this cell is placed in a solution with Ψ = -0.3 MPa, will water move into or out of the cell? Show your work.

💡 Show Solution

Given:

  • Cell solute potential: Ψ_s = -0.5 MPa
  • Cell pressure potential: Ψ_p = 0.3 MPa
  • Solution water potential: Ψ_solution = -0.3 MPa

Step 1: Calculate cell water potential

Ψcell=Ψs+Ψp\Psi_{cell} = \Psi_s + \Psi_p

Ψcell=(0.5)+(0.3)\Psi_{cell} = (-0.5) + (0.3)

Ψcell=0.2 MPa\boxed{\Psi_{cell} = -0.2 \text{ MPa}}

Step 2: Determine direction of water movement

Water moves from higher (less negative) to lower (more negative) water potential.

Compare:

  • Ψcell=0.2\Psi_{cell} = -0.2 MPa
  • Ψsolution=0.3\Psi_{solution} = -0.3 MPa

Since 0.2>0.3-0.2 > -0.3:

Water moves OUT of the cell into the solution\boxed{\text{Water moves OUT of the cell into the solution}}

Step 3: Explanation

The cell has a higher (less negative) water potential than the surrounding solution, so water flows out by osmosis.

What happens to the cell:

  • Water exits the cell
  • Cell becomes flaccid (loses turgor)
  • May undergo plasmolysis (membrane pulls away from cell wall)
  • Ψ_p decreases as cell loses water
  • Eventually reaches equilibrium when Ψcell=Ψsolution\Psi_{cell} = \Psi_{solution}

Key Concept: Water always flows from high Ψ to low Ψ. More negative = lower water potential = less "free" water available.

Direction: CellwaterSolution\text{Direction: Cell} \xrightarrow{\text{water}} \text{Solution}

12Problem 12hard

Question:

Calculate the water potential (Ψ) of a plant cell with a solute potential (Ψ_s) of -0.5 MPa and a pressure potential (Ψ_p) of 0.3 MPa. If this cell is placed in a solution with Ψ = -0.3 MPa, will water move into or out of the cell? Show your work.

💡 Show Solution

Given:

  • Cell solute potential: Ψ_s = -0.5 MPa
  • Cell pressure potential: Ψ_p = 0.3 MPa
  • Solution water potential: Ψ_solution = -0.3 MPa

Step 1: Calculate cell water potential

Ψcell=Ψs+Ψp\Psi_{cell} = \Psi_s + \Psi_p

Ψcell=(0.5)+(0.3)\Psi_{cell} = (-0.5) + (0.3)

Ψcell=0.2 MPa\boxed{\Psi_{cell} = -0.2 \text{ MPa}}

Step 2: Determine direction of water movement

Water moves from higher (less negative) to lower (more negative) water potential.

Compare:

  • Ψcell=0.2\Psi_{cell} = -0.2 MPa
  • Ψsolution=0.3\Psi_{solution} = -0.3 MPa

Since 0.2>0.3-0.2 > -0.3:

Water moves OUT of the cell into the solution\boxed{\text{Water moves OUT of the cell into the solution}}

Step 3: Explanation

The cell has a higher (less negative) water potential than the surrounding solution, so water flows out by osmosis.

What happens to the cell:

  • Water exits the cell
  • Cell becomes flaccid (loses turgor)
  • May undergo plasmolysis (membrane pulls away from cell wall)
  • Ψ_p decreases as cell loses water
  • Eventually reaches equilibrium when Ψcell=Ψsolution\Psi_{cell} = \Psi_{solution}

Key Concept: Water always flows from high Ψ to low Ψ. More negative = lower water potential = less "free" water available.

Direction: CellwaterSolution\text{Direction: Cell} \xrightarrow{\text{water}} \text{Solution}