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Heat and Specific Heat

Heat transfer, specific heat capacity, and calorimetry

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🔥 Heat and Specific Heat

Heat vs. Temperature

Temperature: Measure of average kinetic energy of particles Heat (Q): Energy transferred between objects due to temperature difference

💡 Key Distinction: Temperature is a property; heat is energy in transit.

Heat flows spontaneously from hot to cold until thermal equilibrium is reached.


Units of Heat

  • Joule (J): SI unit of energy
  • Calorie (cal): Energy to raise 1 g of water by 1°C
    • 1 cal = 4.186 J
  • Kilocalorie (kcal or Cal): Food "Calorie"
    • 1 kcal = 1000 cal = 4186 J

Specific Heat Capacity

Specific heat (c) is the energy required to raise the temperature of 1 kg of a substance by 1°C (or 1 K).

Q=mcΔTQ = mc\Delta T

where:

  • QQ = heat transferred (J)
  • mm = mass (kg)
  • cc = specific heat (J/kg·°C or J/kg·K)
  • ΔT\Delta T = temperature change (°C or K)

Common Specific Heats:

Substancec (J/kg·°C)
Water4186
Ice2090
Steam2010
Aluminum900
Steel470
Copper387
Lead128

Water has the highest specific heat of common substances! This is why:

  • Coastal areas have moderate climates
  • Water is used in cooling systems
  • Land heats/cools faster than oceans

Sign Convention

  • Q>0Q > 0: Heat absorbed (temperature increases)
  • Q<0Q < 0: Heat released (temperature decreases)

ΔT=Tfinal−Tinitial\Delta T = T_{final} - T_{initial}

If ΔT>0\Delta T > 0: temperature increases → heat absorbed If ΔT<0\Delta T < 0: temperature decreases → heat released


Calorimetry

Calorimetry measures heat transfer using conservation of energy.

Principle: In an isolated system, heat lost = heat gained

Qlost+Qgained=0Q_{lost} + Q_{gained} = 0

or

∑Qi=0\sum Q_i = 0

Typical Setup:

  • Hot object placed in cold water
  • System isolated (insulated calorimeter)
  • Final temperature measured
  • Energy conservation: Qhot+Qcold=0Q_{hot} + Q_{cold} = 0

Heat Capacity

Heat capacity (C) is heat needed to raise an object's temperature by 1°C:

C=mcC = mc

Q=CΔTQ = C\Delta T

Units: J/°C

Difference:

  • Specific heat (c): Property of material (per kg)
  • Heat capacity (C): Property of specific object (total)

Methods of Heat Transfer

1. Conduction

  • Heat transfer through direct contact
  • Molecular collisions
  • Requires material medium
  • Example: Metal spoon in hot soup

2. Convection

  • Heat transfer by fluid motion
  • Hot fluid rises, cold sinks
  • Requires fluid (liquid or gas)
  • Example: Boiling water, ocean currents

3. Radiation

  • Heat transfer by electromagnetic waves
  • No medium required (works in vacuum)
  • All objects emit thermal radiation
  • Example: Sun warming Earth, heat lamps

Problem-Solving Strategy

  1. Identify all objects exchanging heat
  2. Set up energy conservation: ∑Q=0\sum Q = 0
  3. Write Q for each object: Q=mcΔTQ = mc\Delta T
  4. Determine signs:
    • Heating: Q>0Q > 0, ΔT>0\Delta T > 0
    • Cooling: Q<0Q < 0, ΔT<0\Delta T < 0
  5. Solve for unknown (usually final temperature or specific heat)
  6. Check reasonableness: Final T should be between initial temperatures

Common Mistakes

❌ Using wrong sign for heat (lost vs. gained) ❌ Forgetting to convert units (g → kg, cal → J) ❌ Using Celsius in place of Kelvin inappropriately (ΔT is same, but not absolute T) ❌ Neglecting heat lost to surroundings (real calorimeters aren't perfectly insulated) ❌ Mixing up specific heat (c) and heat capacity (C)

📚 Practice Problems

1Problem 1easy

❓ Question:

How much heat is required to raise the temperature of 2.0 kg of water from 20°C to 80°C? (c_water = 4186 J/kg·°C)

💡 Show Solution

Given:

  • Mass: m=2.0m = 2.0 kg
  • Initial temp: Ti=20°CT_i = 20°\text{C}
  • Final temp: Tf=80°CT_f = 80°\text{C}
  • Specific heat: c=4186c = 4186 J/kg·°C

Find: Heat required QQ

Solution:

Step 1: Calculate temperature change. ΔT=Tf−Ti=80−20=60°C\Delta T = T_f - T_i = 80 - 20 = 60°\text{C}

Step 2: Apply heat formula. Q=mcΔTQ = mc\Delta T Q=(2.0)(4186)(60)Q = (2.0)(4186)(60) Q=502,320 J=502 kJQ = 502,320 \text{ J} = 502 \text{ kJ}

Answer: 502 kJ of heat is required

This is equivalent to about 120 food Calories (kcal).

2Problem 2easy

❓ Question:

How much heat is required to raise the temperature of 2.0 kg of water from 20°C to 80°C? (c_water = 4186 J/kg·°C)

💡 Show Solution

Given:

  • Mass: m=2.0m = 2.0 kg
  • Initial temp: Ti=20°CT_i = 20°\text{C}
  • Final temp: Tf=80°CT_f = 80°\text{C}
  • Specific heat: c=4186c = 4186 J/kg·°C

Find: Heat required QQ

Solution:

Step 1: Calculate temperature change. ΔT=Tf−Ti=80−20=60°C\Delta T = T_f - T_i = 80 - 20 = 60°\text{C}

Step 2: Apply heat formula. Q=mcΔTQ = mc\Delta T Q=(2.0)(4186)(60)Q = (2.0)(4186)(60) Q=502,320 J=502 kJQ = 502,320 \text{ J} = 502 \text{ kJ}

Answer: 502 kJ of heat is required

This is equivalent to about 120 food Calories (kcal).

3Problem 3medium

❓ Question:

A 0.50 kg piece of aluminum at 100°C is dropped into 2.0 kg of water at 20°C. What is the final equilibrium temperature? (c_Al = 900 J/kg·°C, c_water = 4186 J/kg·°C)

💡 Show Solution

Given:

  • Aluminum: mAl=0.50m_{Al} = 0.50 kg, TAl,i=100°CT_{Al,i} = 100°\text{C}, cAl=900c_{Al} = 900 J/kg·°C
  • Water: mw=2.0m_w = 2.0 kg, Tw,i=20°CT_{w,i} = 20°\text{C}, cw=4186c_w = 4186 J/kg·°C

Find: Final temperature TfT_f

Solution:

Step 1: Set up energy conservation. QAl+Qw=0Q_{Al} + Q_w = 0 mAlcAlΔTAl+mwcwΔTw=0m_{Al}c_{Al}\Delta T_{Al} + m_w c_w \Delta T_w = 0

Step 2: Express temperature changes. mAlcAl(Tf−TAl,i)+mwcw(Tf−Tw,i)=0m_{Al}c_{Al}(T_f - T_{Al,i}) + m_w c_w(T_f - T_{w,i}) = 0

Step 3: Substitute values. (0.50)(900)(Tf−100)+(2.0)(4186)(Tf−20)=0(0.50)(900)(T_f - 100) + (2.0)(4186)(T_f - 20) = 0 450(Tf−100)+8372(Tf−20)=0450(T_f - 100) + 8372(T_f - 20) = 0 450Tf−45,000+8372Tf−167,440=0450T_f - 45,000 + 8372T_f - 167,440 = 0 8822Tf=212,4408822T_f = 212,440 Tf=24.1°CT_f = 24.1°\text{C}

Verification:

  • Aluminum cools: ΔTAl=24.1−100=−75.9°C\Delta T_{Al} = 24.1 - 100 = -75.9°\text{C} ✓
  • Water warms: ΔTw=24.1−20=4.1°C\Delta T_w = 24.1 - 20 = 4.1°\text{C} ✓
  • Final T between initial temperatures ✓

Answer: Final temperature is 24.1°C

The water barely warms because it has much larger mass and specific heat!

4Problem 4medium

❓ Question:

A 0.50 kg piece of aluminum at 100°C is dropped into 2.0 kg of water at 20°C. What is the final equilibrium temperature? (c_Al = 900 J/kg·°C, c_water = 4186 J/kg·°C)

💡 Show Solution

Given:

  • Aluminum: mAl=0.50m_{Al} = 0.50 kg, TAl,i=100°CT_{Al,i} = 100°\text{C}, cAl=900c_{Al} = 900 J/kg·°C
  • Water: mw=2.0m_w = 2.0 kg, Tw,i=20°CT_{w,i} = 20°\text{C}, cw=4186c_w = 4186 J/kg·°C

Find: Final temperature TfT_f

Solution:

Step 1: Set up energy conservation. QAl+Qw=0Q_{Al} + Q_w = 0 mAlcAlΔTAl+mwcwΔTw=0m_{Al}c_{Al}\Delta T_{Al} + m_w c_w \Delta T_w = 0

Step 2: Express temperature changes. mAlcAl(Tf−TAl,i)+mwcw(Tf−Tw,i)=0m_{Al}c_{Al}(T_f - T_{Al,i}) + m_w c_w(T_f - T_{w,i}) = 0

Step 3: Substitute values. (0.50)(900)(Tf−100)+(2.0)(4186)(Tf−20)=0(0.50)(900)(T_f - 100) + (2.0)(4186)(T_f - 20) = 0 450(Tf−100)+8372(Tf−20)=0450(T_f - 100) + 8372(T_f - 20) = 0 450Tf−45,000+8372Tf−167,440=0450T_f - 45,000 + 8372T_f - 167,440 = 0 8822Tf=212,4408822T_f = 212,440 Tf=24.1°CT_f = 24.1°\text{C}

Verification:

  • Aluminum cools: ΔTAl=24.1−100=−75.9°C\Delta T_{Al} = 24.1 - 100 = -75.9°\text{C} ✓
  • Water warms: ΔTw=24.1−20=4.1°C\Delta T_w = 24.1 - 20 = 4.1°\text{C} ✓
  • Final T between initial temperatures ✓

Answer: Final temperature is 24.1°C

The water barely warms because it has much larger mass and specific heat!

5Problem 5medium

❓ Question:

A 200 g aluminum cup (c = 900 J/(kg·°C)) contains 500 g of water (c = 4186 J/(kg·°C)) at 20°C. A 100 g piece of copper (c = 387 J/(kg·°C)) at 80°C is placed in the water. Find the final equilibrium temperature.

💡 Show Solution

Solution:

Given:

  • Al cup: m₁ = 0.200 kg, c₁ = 900 J/(kg·°C), T₁ = 20°C
  • Water: m₂ = 0.500 kg, c₂ = 4186 J/(kg·°C), T₂ = 20°C
  • Cu: m₃ = 0.100 kg, c₃ = 387 J/(kg·°C), T₃ = 80°C

Energy conservation: Heat lost by copper = Heat gained by water + aluminum

m₃c₃(T₃ - T_f) = m₁c₁(T_f - T₁) + m₂c₂(T_f - T₂)

Since T₁ = T₂ = 20°C: (0.100)(387)(80 - T_f) = (0.200)(900)(T_f - 20) + (0.500)(4186)(T_f - 20)

3096 - 38.7T_f = 180T_f - 3600 + 2093T_f - 41,860 3096 - 38.7T_f = 2273T_f - 45,460 48,556 = 2311.7T_f T_f = 21.0°C

The large mass and high specific heat of water dominates.

6Problem 6hard

❓ Question:

A 0.20 kg piece of unknown metal at 150°C is placed in 0.50 kg of water at 20°C. The final temperature is 25°C. What is the specific heat of the metal? Assume no heat is lost to surroundings. (c_water = 4186 J/kg·°C)

💡 Show Solution

Given:

  • Metal: mm=0.20m_m = 0.20 kg, Tm,i=150°CT_{m,i} = 150°\text{C}, cm=?c_m = ?
  • Water: mw=0.50m_w = 0.50 kg, Tw,i=20°CT_{w,i} = 20°\text{C}, cw=4186c_w = 4186 J/kg·°C
  • Final: Tf=25°CT_f = 25°\text{C}

Find: Specific heat of metal cmc_m

Solution:

Step 1: Set up energy conservation. Qm+Qw=0Q_m + Q_w = 0 mmcmΔTm+mwcwΔTw=0m_m c_m \Delta T_m + m_w c_w \Delta T_w = 0

Step 2: Calculate temperature changes. ΔTm=25−150=−125°C\Delta T_m = 25 - 150 = -125°\text{C} ΔTw=25−20=5°C\Delta T_w = 25 - 20 = 5°\text{C}

Step 3: Solve for cmc_m. mmcmΔTm=−mwcwΔTwm_m c_m \Delta T_m = -m_w c_w \Delta T_w cm=−mwcwΔTwmmΔTmc_m = -\frac{m_w c_w \Delta T_w}{m_m \Delta T_m} cm=−(0.50)(4186)(5)(0.20)(−125)c_m = -\frac{(0.50)(4186)(5)}{(0.20)(-125)} cm=−10,465−25c_m = -\frac{10,465}{-25} cm=419 J/kg⋅°Cc_m = 419 \text{ J/kg·°C}

Comparison with known metals:

  • Copper: 387 J/kg·°C
  • Steel: 470 J/kg·°C

Answer: Specific heat is 419 J/kg·°C

This is close to copper (387) or possibly a copper alloy.

7Problem 7medium

❓ Question:

How much heat is required to raise the temperature of 2.0 kg of water from 20°C to 80°C? Use c_water = 4186 J/(kg·°C).

💡 Show Solution

Solution:

Given: m = 2.0 kg, c = 4186 J/(kg·°C), ΔT = 80 - 20 = 60°C

Heat required: Q = mcΔT Q = (2.0)(4186)(60) Q = 5.02 × 10⁵ J or 502 kJ

8Problem 8hard

❓ Question:

A 0.20 kg piece of unknown metal at 150°C is placed in 0.50 kg of water at 20°C. The final temperature is 25°C. What is the specific heat of the metal? Assume no heat is lost to surroundings. (c_water = 4186 J/kg·°C)

💡 Show Solution

Given:

  • Metal: mm=0.20m_m = 0.20 kg, Tm,i=150°CT_{m,i} = 150°\text{C}, cm=?c_m = ?
  • Water: mw=0.50m_w = 0.50 kg, Tw,i=20°CT_{w,i} = 20°\text{C}, cw=4186c_w = 4186 J/kg·°C
  • Final: Tf=25°CT_f = 25°\text{C}

Find: Specific heat of metal cmc_m

Solution:

Step 1: Set up energy conservation. Qm+Qw=0Q_m + Q_w = 0 mmcmΔTm+mwcwΔTw=0m_m c_m \Delta T_m + m_w c_w \Delta T_w = 0

Step 2: Calculate temperature changes. ΔTm=25−150=−125°C\Delta T_m = 25 - 150 = -125°\text{C} ΔTw=25−20=5°C\Delta T_w = 25 - 20 = 5°\text{C}

Step 3: Solve for cmc_m. mmcmΔTm=−mwcwΔTwm_m c_m \Delta T_m = -m_w c_w \Delta T_w cm=−mwcwΔTwmmΔTmc_m = -\frac{m_w c_w \Delta T_w}{m_m \Delta T_m} cm=−(0.50)(4186)(5)(0.20)(−125)c_m = -\frac{(0.50)(4186)(5)}{(0.20)(-125)} cm=−10,465−25c_m = -\frac{10,465}{-25} cm=419 J/kg⋅°Cc_m = 419 \text{ J/kg·°C}

Comparison with known metals:

  • Copper: 387 J/kg·°C
  • Steel: 470 J/kg·°C

Answer: Specific heat is 419 J/kg·°C

This is close to copper (387) or possibly a copper alloy.

Explain using:

📌 Related Topics in Thermodynamics

❓ Frequently Asked Questions

What is Heat and Specific Heat?▾
Heat transfer, specific heat capacity, and calorimetry
How can I study Heat and Specific Heat effectively?▾
Start by reading the study notes and working through the examples on this page. Then use the flashcards to test your recall. Practice with the 8 problems provided, checking solutions as you go. Regular review and active practice are key to retention.
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What course covers Heat and Specific Heat?▾
Heat and Specific Heat is part of the AP Physics 2 course on Study Mondo, specifically in the Thermodynamics section. You can explore the full course for more related topics and practice resources.
Are there practice problems for Heat and Specific Heat?▾
Yes, this page includes 8 practice problems with detailed solutions. Each problem includes a step-by-step explanation to help you understand the approach.